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ORGANIC CHEMISTRY BY DR ANTHONY · 6d ago

Control of stereoselectivity of benzylic hydroxylation catalysed by wild-type cytochrome P450BM3 using decoy molecules

Control of stereoselectivity of benzylic hydroxylation catalysed by wild-type cytochrome P450BM3 using decoy molecules Catal. Sci. Technol., 2017, Advance Article DOI: 10.1039/C7CY01130J, Pa...
ORGANIC CHEMISTRY BY DR ANTHONY · 2W ago

Atom- and step-economical nucleophilic arylation of azaaromatics via electrochemical oxidative cross C-C coupling reactions

Originally posted on Green Chemistry International: Atom- and step-economical nucleophilic arylation of azaaromatics via electrochemical oxidative cross C-C coupling reactions Green Chem., 2...
ORGANIC CHEMISTRY BY DR ANTHONY · 3W ago

Selective synthesis of dimethoxyethane via directly catalytic etherification of crude ethylene glycol

Originally posted on Green Chemistry International: Selective synthesis of dimethoxyethane via directly catalytic etherification of crude ethylene glycol Green Chem., 2017, Advance Article D...
ORGANIC CHEMISTRY BY DR ANTHONY · 3W ago

Selective hydrogenation of N-heterocyclic compounds using Ru nanocatalysts in ionic liquids

Originally posted on Green Chemistry International: Selective hydrogenation of N-heterocyclic compounds using Ru nanocatalysts in ionic liquids Green Chem., 2017, 19,2762-2767 DOI: 10.1039/C...
ORGANIC CHEMISTRY BY DR ANTHONY · 3W ago

Is water a suitable solvent for the catalytic amination of alcohols?

Originally posted on Green Chemistry International: Is water a suitable solvent for the catalytic amination of alcohols? Green Chem., 2017, 19,2839-2845 DOI: 10.1039/C7GC00422B, Paper Johann...
ORGANIC CHEMISTRY BY DR ANTHONY · 4W ago

Iridium-catalyzed highly efficient chemoselective reduction of aldehydes in water using formic acid as the hydrogen source

Originally posted on Green Chemistry International: Iridium-catalyzed highly efficient chemoselective reduction of aldehydes in water using formic acid as the hydrogen source Green Chem., 20...
ORGANIC CHEMISTRY BY DR ANTHONY · 1M ago

A Convenient and “Greener” Synthesis of Methyl Nitroacetate

Methyl Nitroacetate (2) Warning: Although no incidents occurred, the intermediates generated, as well as the end product, are energetic and should be handled as if they are explosive materia...
ORGANIC CHEMISTRY BY DR ANTHONY · 2M ago

NOESY experiment of diastereomer 10α (3S, 5R) …….(3S,5R)-3-Benzyl-5-isobutyl-1,3,4,5-tetrahydro-2H-thieno[3,2-e]- [1,4]diazepin-2-one (10α)

NOESY experiment of diastereomer 10α (3S, 5R) (3S,5R)-3-Benzyl-5-isobutyl-1,3,4,5-tetrahydro-2H-thieno[3,2-e]- [1,4]diazepin-2-one (10α): Pale yellow solid, 50% (64.0 mg), m.p. 66.7–67.4 °C....
ORGANIC CHEMISTRY BY DR ANTHONY · 2M ago

trans-2-(benzo[d][1,3]dioxol-5-yl)-2-methylcyclopropane-1-carbonitrile

trans-2-(benzo[d][1,3]dioxol-5-yl)-2-methylcyclopropane-1-carbonitrile yellowish solid (53 mg, 66%); m.p. = 72 °C; 1 H-NMR (600 MHz, CDCl3): δ = 6.77 – 6.71 (m, 3H), 5.94 (s, 2H), 1.63 – 1.5...
ORGANIC CHEMISTRY BY DR ANTHONY · 4M ago

2-{[6-Chloro-3-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl]methyl}-4-fluorobenzonitrile

2-{[6-Chloro-3-methyl-2,4-dioxo-3,4-dihydropyrimidin-1(2H)-yl]methyl}-4-fluorobenzonitrile (4) white solid . Mp: 193–195 °C. 1H NMR (400 MHz, CDCl3) δ (ppm): 7.74–7.76(m, 1H), 7.14–7.17 (m, ...